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Tosoh Bioscience LLC: The Chemistry of Innovation
Normal Phase / Hydrophilic Interaction
HPLC Columns
Affinity
Hydrophobic Interaction
Ion Exchange
Normal Phase / HILIC
TSKgel Amide-80
TSKgel NH2-100
Reversed Phase
Size Exclusion
Custom Columns
Parts and Accessories


TSKgel Amide-80 columns are packed with 3, 5, or 10µm spherical silica particles that are covalently bonded with carbamoyl groups. The amide stationary phase provides a unique selectivity under regular normal phase conditions or in the hydrophilic interaction mode of chromatography.  Target applications include the analysis of saccharides, glycans, oligosaccarides, peptides and polar compounds from natural products. Unique advantages of Amide-80 phase for saccharide analysis include novel hydrogen bonding retention mechanism between hydroxyl groups of the sample and the carbamoyl group in the stationary phase. The stationary phase does not react with reducing sugars and can be used at elevated temperatures (4 to 80 °C) to prevent peak splitting of carbohydrates that can occur at lower temperatures. In addition, the new, high efficiency, 3µm columns offer shorter analysis time and enhanced sensitivity for LC-MS applications.

The pore size of the bonded phase is indicated by the number in the product description, in this case TSKgel Amide-80 has 80Å nominal pore size.  The nominal pore size of the starting base silica is 100Å.

Now available: TSKgel Amide-80 HR column in 5µm, 4.6mm ID x 25cm size. These new columns are prepared from the same 5 micron packing material and thus offer the same selectivity as existing 5µm TSK-GEL Amide-80 columns. In contrast to traditional 25cm x 4.6mm TSK-GEL Amide-80 columns, the new TSK-GEL Amide-80 HR columns offer higher specifications for plate count (N = > 18,000 vs. 8,000).  Because HR columns are prepared from the same bonded phase lots as standard 5 micron TSK-GEL Amide-80 columns, the only change you will notice is more efficient chromatography!

 

Structure:
Product Attributes:

 Pore size (silica): 100Å
 Particle size (mean): 3, 5 or 10µm
 pH stability: 2.0 - 7.5
 Functional group: Carbamoyl
 Max. temperature (°C): 80
 Surface area
 (m2/g)
450



Literature:

Application Note -- Glycosylation analysis by hydrophilic interaction chromatography (HILIC) - N-Glyco mapping of the ZP-domain of murine TGFR-3

Application Note - Separation of Peptides by Hydrophilic Interaction Chromatography using TSKgel Amide-80

Application Note - TSK-GEL Amide-80 Normal Phase Chromatography Columns for the Separation of Saccharides - Now Available in 3μm!

Application Note -- TSK-GEL Amide-80 HILIC Columns for the Analysis of Melamine and Cyanuric Acid in Milk by LC-MS/MS

Brochure -- Reversed Phase and HILIC TSK-GEL HPLC Columns

Catalog -- Chromatography Catalog, NPC/HILIC columns

Operating Conditions and Specifications

Performance Data -- TSKgel Amide-80 Columns for the Analysis of Hydrophilic Compounds

Product Overview -- TSK-GEL Amide-80 Columns

Separation Report 55 - Separation of Saccharides Using TSK-GEL Amide-80, a Packing Material for High-Performance Normal Phase Partition Chromatography (part 1)

Separation Report 79 - Separation of Saccharides Using TSK-GEL Amide-80, a Packing Material for High Performance Normal Phase Partition Chromatography, Part 2

Technical Presentation -- Newly developed, high performance HILIC columns for use in pharmaceutical analysis by LC/MS

 Applications


 Separation of polyalcohols on TSKgel Amide-80



Separation of pyridylaminated N-glycans from mouse brain on TSKgel Amide-80, 3µm



Ordering information:
To place an order please click on the shopping cart next to the desired item, or contact Customer Service. Tosoh Bioscience LLC only accepts orders from customers in North and South America. For sales offices in other parts of the world, please click Locations.

P/N

3µm products

Particle
size

Housing material

ID
(mm)

Length
(cm)

Price ($)

21864

TSKgel Amide-80

3µm

Stainless Steel

2

5

725Add to Cart

21865

TSKgel Amide-80

3µm

Stainless Steel

2

15

765Add to Cart

21866

TSKgel Amide-80

3µm

Stainless Steel

4.6

5

742Add to Cart

21867

TSKgel Amide-80

3µm

Stainless Steel

4.6

15

809Add to Cart

21862

Guard Cartridge for 2mmID columns, 3pk

3µm

Stainless Steel

2

1

329Add to Cart

19308

Guard Cartridge Holder for 2mm ID cartridges

Stainless Steel

2

1

301Add to Cart

21863

Guard Cartridge for 4.6mmID columns, 3pk

3µm

Stainless Steel

3.2

1.5

231Add to Cart

19018

Guard Cartridge Holder for 3.2mm ID cartridges

Stainless Steel

3.2

1.5

302Add to Cart

P/N

5µm products

Particle
size

Housing material

ID
(mm)

Length
(cm)

Price ($)

21982

TSKgel Amide-80 HR

5µm

Stainless Steel

4.6

25

804Add to Cart

20009

TSKgel Amide-80

5µm

Stainless Steel

1

5

655Add to Cart

20010

TSKgel Amide-80

5µm

Stainless Steel

1

10

701Add to Cart

21486

TSKgel Amide-80

5µm

Stainless Steel

1

15

708Add to Cart

21487

TSKgel Amide-80

5µm

Stainless Steel

1

25

743Add to Cart

19694

TSKgel Amide-80

5µm

Stainless Steel

2

5

667Add to Cart

19695

TSKgel Amide-80

5µm

Stainless Steel

2

10

701Add to Cart

19696

TSKgel Amide-80

5µm

Stainless Steel

2

15

708Add to Cart

19697

TSKgel Amide-80

5µm

Stainless Steel

2

25

743Add to Cart

19532

TSKgel Amide-80

5µm

Stainless Steel

4.6

5

682Add to Cart

19533

TSKgel Amide-80

5µm

Stainless Steel

4.6

10

733Add to Cart

13071

TSKgel Amide-80

5µm

Stainless Steel

4.6

25

767Add to Cart

21941

Guard Cartridge for 2mm ID columns, 3 pk, Replaces P/N 42140

5µm

Stainless Steel

2

1

329Add to Cart

19308

Guard Cartridge holder for for 2mm ID cartridges

Stainless Steel

2

1

301Add to Cart

19021

Guard Column for 4.6mm ID columns

5µm

Stainless Steel

4.6

1

191Add to Cart

19010

Guard Cartridge for 4.6mm ID columns, 3 pk

5µm

Stainless Steel

3.2

1.5

231Add to Cart

19018

Guard Cartridge Holder for 3.2mm ID cartridges

Stainless Steel

3.2

1.5

302Add to Cart

P/N

10µm products

Particle
size

Housing material

ID
(mm)

Length
(cm)

Price ($)

14459

TSKgel Amide-80

10µm

Stainless Steel

7.8

30

1,412Add to Cart

14460

TSKgel Amide-80

10µm

Stainless Steel

21.5

30

3,594Add to Cart

14461

Guard column for P/N 14460

5µm

Stainless Steel

21.5

7.5

1,007Add to Cart


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